Long-term self-assembly of inorganic layered materials influenced by the local states of the interlayer cations

Literature Information

Publication Date 2014-04-22
DOI 10.1039/C4CP00990H
Impact Factor 3.676
Authors

Kiminori Sato, Kazuomi Numata, Weili Dai, Michael Hunger


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Abstract

A wide variety of parameters as, e.g., temperature, humidity, particle size, and cation state are known to influence the agglomeration process of two-dimensional (2D) nanosheets, called self-assembly, in inorganic layered materials. The detailed studies on which parameters are decisive and how they influence the self-assembly, however, have not been performed yet. Here, the long-term self-assembly was studied for layered stevensite and hectorite, and compared with our previous data of saponite for elucidating an influence of local states of the interlayer cations. The results were analyzed with respect to a recently established rheological model, in which 2D nanosheets migrate parallel to the layer direction aided by water molecules as lubricants [K. Sato et al., J. Phys. Chem. C, 2012, 116, 22954]. With decreasing the strength of the local electric fields facing to the interlayer spaces, cation positions split into two or three, which makes the distribution of water molecules more uniformly. These water molecules enhance the rheological motion of the 2D nanosheets parallel to the layer direction, thus accelerating the self-assembly process.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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