Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate
Literature Information
Publication Date
2013-09-23
DOI
10.1039/C3PY01128C
Impact Factor
5.582
Authors
Daniel P. Sanders, Daniel J. Coady, Manabu Yasumoto, Masaki Fujiwara, Haritz Sardon, James L. Hedrick
View Original
Abstract
Functionalized cyclic carbonate monomers were synthesized via a two step route featuring a novel cyclic carbonate intermediate possessing a pendent activated pentafluorophenyl carbonate group (MTC-PFPC). The pentafluorophenyl carbonate of MTC-PFPC was selectively substituted with suitable nucleophiles such as alcohols, amines and thiols generating functionalized cyclic carbonates in moderate to high yield.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride
CAS Number:
1329799-67-8
Molecular Formula:
C7H2ClD6NO2
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