AFM study of oxygen reduction products on HOPG in the LiPF6–DMSO electrolyte

Literature Information

Publication Date 2013-12-18
DOI 10.1039/C3CP54621G
Impact Factor 3.676
Authors

Santiago E. Herrera, Alvaro Y. Tesio, Romain Clarenc, Ernesto J. Calvo


View Original

Abstract

Ex situ atomic force microscopy (AFM) has been used to study the morphology of oxygen reduction products in the LiPF6–dimethyl sulfoxide (DMSO) electrolyte, i.e. Li2O2 on a highly oriented pyrolytic graphite (HOPG) surface. Both cyclic voltammetry and chronoamperometry have shown that at low cathodic polarization the initial deposits decorate the edge steps of HOPG. At higher overpotentials a massive deposit covers the terraces. Upon charging the battery cathode Li2O2 oxidation and dissolution do not take place until high overpotentials are reached at which solvent decomposition has been demonstrated by in situ FTIR studies.

Related Literature

Tunable regiodivergent phosphine-catalyzed [3 + 2] cycloaddition of alkynones and trifluoroacetyl phenylamides

Yao-Liang Sun, Yin Wei

2017-08-29 Research Article

DOI: 10.1039/C7QO00512A

Ir(iii)-Catalyzed site-selective amidation of azoxybenzenes and late-stage transformation

Wenge Zhang, Hong Deng, Hongji Li

2017-08-11 Research Article

DOI: 10.1039/C7QO00542C

Anion-induced isomerization of fluorescent semi(thio)carbazones

Valeria Amendola, Massimo Boiocchi, Luigi Fabbrizzi, Sonia La Cognata, Laura Legnani, Eliana Lo Presti, Carlo Mangano, Ana Miljkovic

2017-10-11 Research Article

DOI: 10.1039/C7QO00805H

Front cover

Cover

DOI: 10.1039/C7QO90033C

Rearranged limonoids with unique 6/5/6/5 tetracarbocyclic skeletons from Toona ciliata and biomimetic structure divergence

Jun Luo, Wan-Sha Huang, Sheng-Mou Hu, Pan-Pan Zhang, Xu-Wei Zhou, Xiao-Bing Wang, Ming-Hua Yang, Jian-Guang Luo, Chen Wang, Chang Liu, He-Quan Yao, Can Zhang, Hong-Bin Sun, Yi-Jun Chen, Ling-Yi Kong

2017-09-06 Research Article

DOI: 10.1039/C7QO00678K

Pd-Catalyzed thiophene directed regioselective functionalization of arenes: a direct approach to multiply-substituted benzyl amines

Jundie Hu, Guobao Li, Zhi-Bin Huang, Jingyu Zhang, Da-Qing Shi, Yingsheng Zhao

2017-04-28 Research Article

DOI: 10.1039/C7QO00236J

Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

Yuhan Zhou, Huan Wang, Yang Liu, Yilong Zhao, Chunxia Zhang, Jingping Qu

2017-05-10 Research Article

DOI: 10.1039/C7QO00228A

Ball-milling and cheap reagents breathe green life into the one hundred-year-old Hofmann reaction

Rita Mocci, Sergio Murgia, Lidia De Luca, Francesco Delogu, Andrea Porcheddu

2017-12-11 Research Article

DOI: 10.1039/C7QO01006K

Synthesis of withasomnine and pyrazole derivatives via intramolecular dehydrogenative cyclization, as well as biological evaluation of withasomnine-based scaffolds

Tingting Xia, Zhenyi Hu, Wenzhi Ji, Shujie Zhang, Hui Shi, Chenguang Liu, Bo Pang, Guijian Liu, Xuebin Liao

2017-11-29 Research Article

DOI: 10.1039/C7QO00847C

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.