Exploring the limits of electron-nuclear polarization transfer efficiency in three-spin systems

Literature Information

Publication Date 2010-05-06
DOI 10.1039/C003751F
Impact Factor 3.676
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Abstract

For three model systems, consisting of one electron spin and two nuclear spins, polarization transfer sequences were optimized using an optimal control based numerical algorithm. This makes it possible to explore the physical limits of achievable nuclear polarization enhancement in such systems. The resulting coherent and incoherent transfer schemes are analyzed and their efficiency is compared with standard DNP approaches.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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