Stepwise in situ synthesis and characterization of metallophthalocyanines@mesoporous matrix SBA-15 composites
Literature Information
Jiangtian Li, Limin Guo, Jianlin Shi
The successful in situ synthesis of metallophthalocyanines in mesoporous matrices is presented in this report. To overcome the high hydrophobicity of phthalocyanine (Pc) compounds in conventional wet chemical methods, a simple but effective route is developed to incorporate the metallophthalocyanines into the mesoporous matrix via an in situ reaction process between pre-loaded metal ions and 1,2-dicyanobenzene (DCB) introduced by chemical vapor deposition. The Pcs are not directly loaded into the pores, but the precursors of metallophthalocyanines (metal ions and small DCB molecules) are introduced stepwise into the pore channels, which are then used as ‘micro-reactors” to produce incorporated MePcs by in situ reactions. The structural and optical characteristics of the as-synthesized composites are carefully investigated using X-ray diffraction, transmission electronic microscopy, scanning electronic microscopy, infrared and ultra violet spectra, and BET methods. The results show that the metallophthalocyanines disperse homogeneously in the mesopores, mostly as monomers, accompanied by a small number of dimers.
Recommended Journals

Environmental Toxicology and Pharmacology

Molecular Diversity

Angewandte Chemie International Edition

Journal of Enzyme inhibition and Medicinal Chemistry

Lab on a Chip

European Journal of Organic Chemistry

Journal of Medical Biochemistry

Coloration Technology

Foundations of Chemistry

Current Pharmaceutical Biotechnology
Related Literature
Detection of the tuberculosis antigenic marker mannose-capped lipoarabinomannan in pretreated serum by surface-enhanced Raman scattering
Lars B. Laurentius, Timothy S. Mulvihill, Jennifer H. Granger, John S. Spencer, Delphi Chatterjee, Kimberly E. Hanson
DOI: 10.1039/C6AN02110G
Accurate quantification of apoptosis progression and toxicity using a dielectrophoretic approach
Erin A. Henslee, Ruth M. Torcal Serrano, Fatima H. Labeed, Rita I. Jabr, Christopher H. Fry, Michael P. Hughes, Kai F. Hoettges
DOI: 10.1039/C6AN01596D
An ultrasensitive electrochemical immunosensor based on the synergistic effect of quaternary Cu2SnZnS4 NCs and cyclodextrin-functionalized graphene
Lei Liu, Yihe Zhang, Ruifeng Du, Jinhong Li, Xuelian Yu
DOI: 10.1039/C6AN02538B
Correction: Continuous and simultaneous measurement of the biophysical properties of blood in a microfluidic environment
DOI: 10.1039/C6AN90102F
Fast voltammetry of metals at carbon-fiber microelectrodes: towards an online speciation sensor
Pavithra Pathirathna, Thushani Siriwardhane, Shawn P. McElmurry, Stephen L. Morgan, Parastoo Hashemi
DOI: 10.1039/C6AN01807F
Detection of evoked acetylcholine release in mouse brain slices
R. Asri, B. O'Neill, J. C. Patel, K. A. Siletti, M. E. Rice
DOI: 10.1039/C6AN01758D
Ultrasensitive detection of nucleic acids based on dually enhanced fluorescence polarization
Bin Wang, Dahai Ren, Zheng You, Yaxiaer Yalikun, Yo Tanaka
DOI: 10.1039/C8AN00952J
Electron spin resonance and fluorescence imaging assisted electrochemical approach for accurate and comprehensive monitoring of cellular hydrogen peroxide dynamics
Qi Xin, Jian Ru Gong
DOI: 10.1039/C6AN02006B
You might also like
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![6,7-Dihydro-5H-pyrrolo[1,2-a]imidazole-6-carboxylic acid structure 6,7-Dihydro-5H-pyrrolo[1,2-a]imidazole-6-carboxylic acid structure](https://static.chemtradehub.com/structs/136/1369160-12-2-6524.webp)

![2,4-Dichloro-6-isopropyl-5H-pyrrolo[3,4-d]pyrimidin-7(6H)-one structure 2,4-Dichloro-6-isopropyl-5H-pyrrolo[3,4-d]pyrimidin-7(6H)-one structure](https://static.chemtradehub.com/structs/107/1079649-94-7-ad4a.webp)

