Oxidation of methanol and formaldehyde to CO2 by a photocatalyst with an energy storage ability
Literature Information
Fei Yang, Yukina Takahashi, Nobuyuki Sakai, Tetsu Tatsuma
A TiO2–Ni(OH)2 bilayer photocatalyst is known as a photocatalyst with energy storage abilities. Oxidative energy from the UV-irradiated TiO2 underlayer can be stored in the Ni(OH)2 overlayer. We investigated oxidation and mineralization of methanol and formaldehyde by the stored oxidative energy by mean of gas chromatography. When the methanol concentration in air is as low as 10 ppm, the mass conversion efficiency from methanol to CO2 is ∼86%. Formaldehyde can also be oxidized to CO2 by the stored energy.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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