A versatile protocol for Stille–Migita cross coupling reactions‡

Literature Information

Publication Date 2008-06-02
DOI 10.1039/B805299A
Impact Factor 6.222
Authors

Alois Fürstner, Jacques-Alexis Funel, Martin Tremblay, Laure C. Bouchez, Cristina Nevado, Mario Waser, Jens Ackerstaff, Christopher C. Stimson


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Abstract

The combination of catalytic amounts of [Pd(PPh3)4], copper thiophene-2-carboxylate (CuTC) and [Ph2PO2][NBu4] allowed a series of exigent Stille–Migita reactions to be performed with high yields; as the protocol is fluoride free, a variety of O-silyl and C-silyl groups remained intact.

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