A rare unsupported iridium(ii) dimer, [IrCl2(CO)2]2

Literature Information

Publication Date 2008-05-02
DOI 10.1039/B803632B
Impact Factor 6.222
Authors

Sanjib K. Patra, S. M. Wahidur Rahaman, Moumita Majumdar, Arup Sinha, Jitendra K. Bera


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Abstract

Oxidative additions of dichloromethanes to a diiridium(I) core, bridged by 2-ferrocenyl-1,8-naphthyridines (NP-Fc), provide an iridium(II) dimer, [IrCl2(CO)2(η1-NP-Fc)]2, featuring an unsupported Ir–Ir single bond (2.7121(8) Å).

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