Hydrogen bonding directs the H2O2oxidation of platinum(ii) to a cis-dihydroxo platinum(iv) complex ‡
Literature Information
Publication Date
2008-04-11
DOI
10.1039/B803370F
Impact Factor
6.222
Authors
Russell A. Taylor, David J. Law, Glenn J. Sunley, Andrew J. P. White, George J. P. Britovsek
View Original
Abstract
The use of ligands with proximate hydrogen bonding substituents in the oxidation of platinum(II) dimethyl complexes with H2O2 leads to the exclusive formation of an unusual cis-dihydroxo platinum(IV) complex, which can dehydrate to form a trinuclear metalla-azacrown complex.
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Source Journal
Chemical Communications
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