Activation of P5R5 (R = Ph, Et) by a Rh-β-diketiminate complex

Literature Information

Publication Date 2008-04-11
DOI 10.1039/B803277G
Impact Factor 6.222
Authors

Stephen J. Geier, Douglas W. Stephan


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Abstract

(NacNac)Rh(C8H14)(N2) reacts with P5R5 to give complexes of formula (NacNac)Rh(P5R5) (R = Ph, Et); in the former species inversion of a P atom of P5Ph5 allows coordination to a Rh(I) centre, whereas in the later species a P–P bond undergoes oxidative addition to give a formally Rh(III) species.

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