Photophysical and photosensitizing properties of brominated porphycenes

Literature Information

Publication Date 2008-04-18
DOI 10.1039/B802730G
Impact Factor 6.222
Authors

Hisashi Shimakoshi, Tatsushi Baba, Yusuke Iseki, Isao Aritome, Ayataka Endo, Chihaya Adachi, Yoshio Hisaeda


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Abstract

A heavy atom, bromine, was directly substituted into the porphycene macrocycle to promote intersystem crossing by way of spin–orbit coupling. The singlet oxygen production ability of the porphycene is dramatically enhanced, and the highest value of 0.95 for the quantum yield of singlet oxygen generation (ΦΔ) was obtained for the dibrominated porphycene by visible light excitation.

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