Stereoselective self-assembly of atropoisomeric Pd(ii) metallocycles induced by an aromatic guest

Literature Information

Publication Date 2008-04-18
DOI 10.1039/B802213E
Impact Factor 6.222
Authors

Dolores Abella, Víctor Blanco, Elena Pía, Marcos Chas, Carlos Platas-Iglesias, Carlos Peinador, José M. Quintela


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Abstract

A new dinuclear Pd(II) metallocycle consisting of a 4,4′-bipyridin-1-ium ligand with a quinoline moiety was self-assembled in aqueous solution with the aid of template molecules; the situation found in solution in which both syn and anti or only the anti atropoisomers are observed strongly relies on the intermolecular host–guest interactions.

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