Synthesis of propargylic fluorides from allenylsilanes
Literature Information
Publication Date
2006-08-23
DOI
10.1039/B610013A
Impact Factor
6.222
Authors
Laurence Carroll, Mª Carmen Pacheco, Ludivine Garcia, Véronique Gouverneur
View Original
Abstract
Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.
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Source Journal
Chemical Communications
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