The structure of the water–hydrogen peroxide complex. A matrix isolation study
Literature Information
Anders Engdahl, Bengt Nelander
The infrared spectrum of the water–hydrogen peroxide complex was studied in argon matrices. The complex is cyclic, with each molecule acting both as a hydrogen bond donor and a hydrogen bond acceptor. The assignment is supported by experiments with combinations of completely and partially deuterated hydrogen peroxide and water. The water–hydrogen peroxide complex is slowly decomposed when irradiated with 266 nm radiation. When the D2O–H2O2 complex is irradiated, H2O–D2O2 forms and ice ersa.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




