Dynamics and dissipation in an externally forced system

Literature Information

Publication Date 2000-08-11
DOI 10.1039/B004443L
Impact Factor 3.676
Authors


View Original

Abstract

We study numerically the influence of periodic and random external perturbations on the oscillating Selkov model by varying one dimensionless parameter, κ, of the model. When the variations of κ are periodic in time, the system responds with bursting oscillations in the case where the forcing frequency is different from the frequency of the oscillations without any perturbations. When the frequencies are almost equal, the system responds to the forcing by oscillating with almost the same frequency as the forcing, but with a higher amplitude linearly proportional to the amplitude of the perturbation. In the second case, κ varies randomly with time. The dynamics are described by stochastic differential equations. The computed ensemble averages of concentrations exhibit a decay or localization of the limit cycle for small amplitudes of the noise. This decay is faster when the amplitude of the noise is higher. As the noise amplitude increases, chaotic behavior begins to appear. For noise amplitudes high enough to push the system away from the oscillatory region, the system exhibits high-amplitude intermittent bursts in the concentrations for different realizations of the noise. We also computed the chemical entropy production for all the cited cases. When κ varies periodically with the same frequency, the entropy production increases nonlinearly with the amplitude of the forcing; the amplitude of the oscillations increases only linearly with the amplitude of the forcing. In general, when the system is periodically forced, strips of high dissipation and valleys of low dissipation exist in the space formed by the amplitude of the perturbation and winding number. In the second case, where κ is random the overall average entropy production is insensitive to the amplitude of the noise as long as κ does not leave the oscillatory region. When κ begins to cross into other regions, the overall average entropy production increases almost linearly with the amplitude of the noise.

Related Literature

Mechanisms of enhanced sulfur tolerance on samarium (Sm)-doped cerium oxide (CeO2) from first principles

Hee Su Kim, Sung Pil Yoon, Jonghee Han, Chang Won Yoon, Sun Hee Choi, Suk Woo Nam, Hyung Chul Ham

2014-04-01 Paper

DOI: 10.1039/C4CP00777H

Structural relaxation of vapor-deposited molecular glasses and supercooled liquids

Kikujiro Ishii, Hideyuki Nakayama

2014-04-24 Perspective

DOI: 10.1039/C4CP00458B

Dinuclear manganese complexes for water oxidation: evaluation of electronic effects and catalytic activity

Wael A. A. Arafa, Markus D. Kärkäs, Bao-Lin Lee, Torbjörn Åkermark, Rong-Zhen Liao, Hans-Martin Berends, Johannes Messinger, Per E. M. Siegbahn, Björn Åkermark

2014-01-27 Paper

DOI: 10.1039/C3CP54800G

Built-in potential shift and Schottky-barrier narrowing in organic solar cells with UV-sensitive electron transport layers

Cheng Li, Dan Credgington, Doo-Hyun Ko, Zhuxia Rong, Jianpu Wang, Neil C. Greenham

2014-04-11 Communication

DOI: 10.1039/C4CP01251H

The free energy of nanopores in tense membranes

Andrea Grafmüller, Volker Knecht

2014-04-15 Paper

DOI: 10.1039/C3CP54685C

Iron near absorption edge X-ray spectroscopy at aqueous-membrane interfaces

Wenjie Wang, Ivan Kuzmenko, David Vaknin

2014-05-23 Paper

DOI: 10.1039/C4CP00657G

Electron transport in MoWSeS monolayers in the presence of an external electric field

Nourdine Zibouche, Pier Philipsen, Thomas Heine, Agnieszka Kuc

2014-04-11 Paper

DOI: 10.1039/C4CP00966E

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.