Phase behaviour of carbon dioxide–benzene–water ternary mixtures at high pressures and temperatures up to 300 MPa and 600 K

Literature Information

Publication Date 2000-08-24
DOI 10.1039/B004198J
Impact Factor 3.676
Authors

Eckhardt Brandt, E. Ulrich Franck, Ya Song Wei, Richard J. Sadus


View Original

Abstract

Experimental measurements of pressure and temperature are reported over a wide composition range for the phase coexistence of carbon dioxide–benzene–water ternary mixtures. Phase coexistence was observed at temperatures and pressures up to 600 K and 300 MPa, respectively. The experimental measurements were determined largely by a “synthetic” method which involved determining “knick-points ” in the temperature–pressure curves supported by additional visual observations. The ternary mixtures exhibit both two-phase/one-phase and three-phase/two-phase transitions. The experimental measurements are supplemented by equation of state calculations using the Guggenheim equation of state in conjunction with conformal solution theory and the one-fluid model.

Related Literature

Insight into the structure and the mechanism of the slow proton transfer in the GFP double mutant T203V/S205A

Ron Simkovitch, Shay Shomer, Rinat Gepshtein, Dan Huppert, Mari Saif, Karen Kallio, S. James Remington

2014-04-14 Paper

DOI: 10.1039/C4CP00311J

Dielectric measurements of aqueous DNA solutions up to 110 GHz

Elena Ermilova, Frank F. Bier, Ralph Hölzel

2014-04-23 Paper

DOI: 10.1039/C3CP55272A

Characterisation of the electronic structure of some stable nitroxyl radicals using variable energy photoelectron spectroscopy

Branka Kovač, Ivan Ljubić, Antti Kivimäki, Marcello Coreno, Igor Novak

2014-04-02 Paper

DOI: 10.1039/C4CP00867G

Non-innocent side-chains with dipole moments in organic solar cells improve charge separation

Hilde D. de Gier, Ria Broer

2014-05-06 Paper

DOI: 10.1039/C4CP01070A

Iron near absorption edge X-ray spectroscopy at aqueous-membrane interfaces

Wenjie Wang, Ivan Kuzmenko, David Vaknin

2014-05-23 Paper

DOI: 10.1039/C4CP00657G

A new interpretation of SAXS peaks in sulfonated poly(ether ether ketone) (sPEEK) membranes for fuel cells

H. Mendil-Jakani, I. Zamanillo Lopez, P. M. Legrand, V. H. Mareau, L. Gonon

2014-04-08 Paper

DOI: 10.1039/C4CP00710G

Solvation dependence of valence electronic states of water diluted in organic solvents probed by soft X-ray spectroscopy

Takashi Tokushima, Yuka Horikawa, Osamu Takahashi, Koichiro Sadakane

2014-04-03 Paper

DOI: 10.1039/C4CP00762J

A water-soluble tin(iv) porphyrin as a bioinspired photosensitiser for light-driven proton-reduction

Anne-Marie Manke, Karen Geisel, Anne Fetzer, Philipp Kurz

2014-01-31 Paper

DOI: 10.1039/C3CP55023K

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.