Magneto-optic measurements of spectral holes in metallo-porphyrin derivatives in polymer matrices

Literature Information

Publication Date 2000-08-29
DOI 10.1039/B003851M
Impact Factor 3.676
Authors

Robin Purchase, Matt Sellars, Elmars Krausz, Neil Manson


View Original

Abstract

Magneto-optic measurements on spectral holes in the Q band of zinc phthalocyanine and zinc tetrabenzoporphyrin are reported. Detailed modelling of the changes in hole shape in the magnetic field requires the inclusion of a broad distribution of crystal-field splittings and a Ham factor of 0.52±0.03. Magnetic circular dichroism (MCD) spectra are also reported for spectral holes in zinc phthalocyanine and zinc tetrabenzoporphyrin. The wavelength dependence of the hole MCD gives insight into the distribution of the crystal-field split levels of the excited state. Modelling of the hole MCD shapes enables a number of factors contributing to the hole MCD shape to be identified.

Related Literature

Effect of amide bonds on the self-assembly of gemini surfactants

Jiaul Hoque, Spandhana Gonuguntla, Venkateswarlu Yarlagadda, Vinod K. Aswal, Jayanta Haldar

2014-04-09 Paper

DOI: 10.1039/C3CP55244F

Pressure dependent OH yields in the reactions of CH3CO and HOCH2CO with O2

C. B. M. Groß, T. J. Dillon, J. N. Crowley

2014-04-28 Paper

DOI: 10.1039/C4CP01108B

Redox hydrogels with adjusted redox potential for improved efficiency in Z-scheme inspired biophotovoltaic cells

Volker Hartmann, Tim Kothe, Sascha Pöller, Eithar El-Mohsnawy, Marc M. Nowaczyk, Nicolas Plumeré, Wolfgang Schuhmann, Matthias Rögner

2014-03-10 Paper

DOI: 10.1039/C4CP00380B

13C NMR relaxation and reorientation dynamics in imidazolium-based ionic liquids: revising interpretation

Petri Ingman, Erkki Lähderanta

2014-04-09 Paper

DOI: 10.1039/C4CP00637B

Non-innocent side-chains with dipole moments in organic solar cells improve charge separation

Hilde D. de Gier, Ria Broer

2014-05-06 Paper

DOI: 10.1039/C4CP01070A

Adsorption and splitting of H2S on 2D-ZnO1−xNy: first-principles analysis

Summayya Kouser, Nacir Tit

2014-04-22 Paper

DOI: 10.1039/C4CP01092B

Effect of chromophore encapsulation on linear and nonlinear optical properties: the case of “miniSOG”, a protein-encased flavin

Nanna H. List, Frederico M. Pimenta, Lotte Holmegaard, Rasmus L. Jensen, Michael Etzerodt, Tobias Schwabe, Jacob Kongsted, Peter R. Ogilby, Ove Christiansen

2014-01-07 Paper

DOI: 10.1039/C3CP54470B

A quasi-classical trajectory study of the OH + SO reaction: the role of ro-vibrational energy

W. A. D. Pires, J. D. Garrido, M. A. C. Nascimento, M. Y. Ballester

2014-05-02 Paper

DOI: 10.1039/C4CP01363H

Electrical conductivity and glass formation in nitrile-functionalized pyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids: chain length and odd–even effects of the alkyl spacer between the pyrrolidinium ring and the nitrile group

Jan Leys, Chandra Shekhar Pati Tripathi, Christ Glorieux, Stefan Zahn, Barbara Kirchner, Stéphane Longuemart, Kallidanthiyil Chellappan Lethesh, Peter Nockemann, Wim Dehaen, Koen Binnemans

2014-03-24 Paper

DOI: 10.1039/C4CP00259H

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.