51V magic angle spinning solid state NMR studies of Bi4V2O11 in oxidized and reduced states

Literature Information

Publication Date 2000-09-14
DOI 10.1039/B003644G
Impact Factor 3.676
Authors

F. Delmaire, M. Rigole, E. A. Zhilinskaya, A. Aboukaïs, R. Hubaut, G. Mairesse


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Abstract

The environment of vanadium in α-Bi4V2O11 was investigated by 51V solid state NMR studies.The NMR parameters used for the best-fit simulations show the presence of at least three different sites of vanadium, two tetrahedral and one bipyramidal trigonal (or distorted octahedral). 51V magic angle spinning NMR spectra obtained at different stages in the reduction of Bi4V2O11 confirm the progressive V(V)–V(IV) reduction. The original upfield shifted signal is attributed to V(V) interacting with paramagnetic V(IV) in Bi4V2O10.66.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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