Concentration fluctuations and nonlinear nonequilibrium thermodynamics

Literature Information

Publication Date 2000-08-23
DOI 10.1039/B002358M
Impact Factor 3.676
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Abstract

The multivariate master equation for a one-step reaction is transformed into a univariate master equation for the density of fluctuation in extent of the reaction. The density of variance of the fluctuation is incorporated into ordinary nonequilibrium thermodynamics of chemical reactions. This makes it possible to formulate a new type of Markov fluctuation–dissipation relations of nonlinear nonequilibrium thermodynamics.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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