Contribution of shape resonance and Pt–H EXAFS in the Pt L2,3 X-ray absorption edges of supported Pt particles: Application and consequences for catalyst characterization

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Publication Date
DOI 10.1039/A900716D
Impact Factor 3.676
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Abstract

The electronic and geometric effects induced by hydrogen chemisorption on small platinum particles supported on high surface-area saponite clay and zeolite LTL were studied by near edge X-ray absorption fine structure (XAFS) spectroscopy. A new subtraction procedure was developed to separate the electronic from geometric effects. A significant Pt–H extended X-ray absorption fine structure (EXAFS) scattering (structural effect) was found for energy values between 0 and 20 eV. In addition, the Pt–H antibonding state (electronic effect) was found to produce a shape-resonance and was isolated from the near edge of the L3 X-ray absorption spectrum. Moreover, for Pt/LTL the shape and energy of the shape-resonance was found to strongly depend on the acidity/alkalinity of the support material, implying a direct influence of the support on the electronic properties of the platinum particles. The results of the study of the resonance state and the Pt–H EXAFS scattering demonstrate the potential of these techniques for characterization of hydrogen chemisorption, metal-promoter, and metal-support effects in catalysis research.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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