A quantitative study of the rapid shrinking kinetics of sub-millimetre N-isopropylacrylamide gels
Literature Information
Sub-millimetre spherical gels of composition 70:10:20 mol% N-isopropylacrylamide:N,N′-tert-butylacrylamide:N,N′-dimethylacrylamide were prepared by inverse suspension polymerisation. The shrinking kinetics of cylindrical and spherical gels of various sizes were determined by image analysis. We are able to describe the shrinking kinetics in the transition region, as, in the size range studied, the gels showed no shape distortion during temperature jumps (T-jumps) to temperatures in the transition region. We define T* to be the temperature at which the gel is fully collapsed, and, for the gels studied, T* is >38°C. All gels relaxed to their equilibrium size exponentially after T-jumps to temperatures below T*(Tf
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure](https://static.chemtradehub.com/structs/210/210532-98-2-f6a7.webp)


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