Sedimentation of colloidal particles near a wall: Stokesian dynamics simulations
Literature Information
We describe a practical approach for computing the mobility matrix of a system of colloidal particles near a hard wall. The approach can be carried out in principle to arbitrary accuracy and number of particles. We make use of this approach to perform Stokesian dynamics computer simulations of colloidal suspensions in both unbounded and bounded fluids. We study finite clusters of particles sedimenting parallel to a nearby hard wall under the influence of a uniform force. The convergence properties of the new scheme, the effect of the wall on the colloidal dynamics, and the additional effect of interparticle and wall–particle potentials are all examined.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.









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